Dichloromethane → 1-O-methanesulfonyl-2-(((1,1-dimethylethyl)diphenylsilyl)oxy)-3-(((1,1-dimethylethyl)di-phenylsilyl)oxymethyl)-1-cyclobutanol

HRID 2157785Notes

Reaction equation

HRID 2157785 reaction equation
[CH2:55]([Cl:56])[Cl:57].[CH3:1][CH2:2][N:3]([CH2:4][CH3:5])[CH2:6][CH3:7].[CH3:50][S:51]([Cl:52])(=[O:53])=[O:54].[CH3:8][C:9]([CH3:10])([CH3:11])[Si:12]([O:13][CH:14]1[CH:15]([OH:37])[CH2:16][CH:17]1[CH2:18][O:19][Si:20]([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)([c:27]1[cH:28][cH:29][cH:30][cH:31][cH:32]1)[C:33]([CH3:34])([CH3:35])[CH3:36])([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)[c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1>>[CH3:8][C:9]([CH3:10])([CH3:11])[Si:12]([O:13][CH:14]1[CH:15]([O:37][S:51]([CH3:50])(=[O:53])=[O:54])[CH2:16][CH:17]1[CH2:18][O:19][Si:20]([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)([c:27]1[cH:28][cH:29][cH:30][cH:31][cH:32]1)[C:33]([CH3:34])([CH3:35])[CH3:36])([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)[c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1

Participants

5

Reactant 4

HCID 6344DichloromethaneHCID 8471TriethylamineHCID 31297Methanesulfonyl chlorideHCID 197943242-O-((1,1-dimethylethyl)diphenylsilyl)-3-(((1,1-dimethylethyl)diphenyl-silyl)oxymethyl)-1,2-cyclobutanediol

Product 1

HCID 197942931-O-methanesulfonyl-2-(((1,1-dimethylethyl)diphenylsilyl)oxy)-3-(((1,1-dimethylethyl)di-phenylsilyl)oxymethyl)-1-cyclobutanol

Sources & evidence

ORD record
ord-6996ab00679f4f918be5fd6ddf0c1140
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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