Dimethyl Sulfoxide → 1-(4-iodophenyl)-2-methyl-1H-imidazole-4-carbaldehyde

HRID 2161398Notes

Reaction equation

HRID 2161398 reaction equation
[CH3:34][S:35]([CH3:36])=[O:37].[CH3:9][c:10]1[nH:11][cH:12][c:13]([CH:15]=[O:16])[n:14]1.[Cu:44][I:45].[I:1][c:2]1[cH:3][cH:4][c:5]([I:8])[cH:6][cH:7]1.[K+:17].[K+:18].[O-:19][C:20]([O-:21])=[O:22].[O:38]1[CH2:39][CH2:40][O:41][CH2:42][CH2:43]1.[OH2:46].[OH:23][c:24]1[cH:25][cH:26][cH:27][c:28]2[c:29]1[n:30][cH:31][cH:32][cH:33]2>>[c:2]1(-[n:11]2[c:10]([CH3:9])[n:14][c:13]([CH:15]=[O:16])[cH:12]2)[cH:3][cH:4][c:5]([I:8])[cH:6][cH:7]1

Participants

10

Reactant 9

HCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 962WaterHCID 19238-HydroxyquinolineHCID 12208p-DiiodobenzeneHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 312751,4-DioxaneHCID 178418999HCID 178418999, compound

Product 1

HCID 593866581-(4-iodophenyl)-2-methyl-1H-imidazole-4-carbaldehyde

Sources & evidence

ORD record
ord-459b68cc5c39421794fdd6be07d50d41
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

Loading…