Potassium Cation → 8-Cyclopropyl-6-ethynyl-3 4-dihydro-4,4-dimethylspiro[2H-1-benzopyran-2,1'-cvclopropane]

HRID 2161648Notes

Reaction equation

[C:26](=[O:27])([O-:28])[O-:29].[CH3:24][OH:25].[CH3:32][CH2:33][O:34][C:35](=[O:36])[CH3:37].[CH3:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43].[CH:1]1([c:4]2[cH:5][c:6]([C:18]#[C:19][Si:20]([CH3:21])([CH3:22])[CH3:23])[cH:7][c:8]3[c:13]2[O:12][C:11]2([CH2:10][C:9]3([CH3:16])[CH3:17])[CH2:14][CH2:15]2)[CH2:2][CH2:3]1.[K+:30].[K+:31]>>[CH:1]1([c:4]2[cH:5][c:6]([C:18]#[CH:19])[cH:7][c:8]3[c:13]2[O:12][C:11]2([CH2:10][C:9]3([CH3:16])[CH3:17])[CH2:14][CH2:15]2)[CH2:2][CH2:3]1

Participants

Reactant 6

HCID 813Potassium Cation2×

HCID 887Methanol

HCID 8058Hexane

HCID 8857Ethyl Acetate

HCID 19660Carbonate Ion

HCID 225688398-Cyclopropyl-3,4-dihydro-4,4-dimethyl-6-(trimethylsilanyl)ethynylspiro[2 H 1-benzopyran-2,1'-cyclopropane]

Product 1

HCID 225689518-Cyclopropyl-6-ethynyl-3 4-dihydro-4,4-dimethylspiro[2H-1-benzopyran-2,1'-cvclopropane]

Sources & evidence

ORD record: ord-d7e1126c00094db0918c5b473be8256a
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (4/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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