HRID2163394

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID516892

Sodium Bicarbonate

CHNaO3

结构：CCCc1ccccc1OCC(O)COc1ccc2oc(C(=O)O)cc(=O)c2c1

HCID13090998

未命名化合物

PRODUCTS

生成物

结构：CCCc1ccccc1OCC(O)COc1ccc2oc(C(=O)[O-])cc(=O)c2c1.CCCc1ccccc1OCC(O)COc1ccc2oc(C(=O)[O-])cc(=O)c2c1.O.[Na+].[Na+]

HCID131710632

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

A mixture of 7.31 parts of 6-[2-hydroxy-3-(2-propylphenoxy)propoxy]-4-oxo-4H-1-benzopyran-2-carboxylic acid and 1.54 parts of sodium bicarbonate in 100 parts of water, was heated to effect solution. The solution was filtered and freeze dried to yield 7.5 parts of sodium 6-[2-hydroxy-3-(2-propylphenoxy)propoxy]-4-oxo-4H-1-benzopyran-2-carboxylate, hemihydrate.

WORKUP

后处理

temperaturewas heated
filtrationThe solution was filtered
customfreeze dried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-94b9e81f714740aca55764a95ee44e46
来源数据集: uspto-grants-1979_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04133889
来源说明: uspto-grants-1979_01

反应 SMILES

[OH:1][CH:2]([CH2:19][O:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=1[CH2:27][CH2:28][CH3:29])[CH2:3][O:4][C:5]1[CH:6]=[CH:7][C:8]2[O:13][C:12]([C:14]([OH:16])=[O:15])=[CH:11][C:10](=[O:17])[C:9]=2[CH:18]=1.C(=O)(O)[O-].[Na+:34]>O>[OH2:1].[OH:1][CH:2]([CH2:19][O:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=1[CH2:27][CH2:28][CH3:29])[CH2:3][O:4][C:5]1[CH:6]=[CH:7][C:8]2[O:13][C:12]([C:14]([O-:16])=[O:15])=[CH:11][C:10](=[O:17])[C:9]=2[CH:18]=1.[Na+:34].[Na+:34].[OH:1][CH:2]([CH2:19][O:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=1[CH2:27][CH2:28][CH3:29])[CH2:3][O:4][C:5]1[CH:6]=[CH:7][C:8]2[O:13][C:12]([C:14]([O-:16])=[O:15])=[CH:11][C:10](=[O:17])[C:9]=2[CH:18]=1