HCID 22749738, compound → HCID 22749858, compound

HRID 2164195Notes

Reaction equation

HRID 2164195 reaction equation
[CH3:1][S:2][C:3]1[CH:8]=[CH:7][C:6]([O:9][CH2:10][CH2:11][CH:12]([CH3:21])[CH2:13][CH2:14][CH2:15][C:16]([O:19][CH3:20])([CH3:18])[CH3:17])=[CH:5][CH:4]=1.CSC1C=CC([O:30]CC=C(C)CCCC(OC)(C)C)=CC=1.[CH3:43][S:44][C:45]1[CH:50]=[CH:49][C:48]([O:51][CH2:52][CH2:53][CH:54]([CH3:64])[CH2:55][CH2:56][CH2:57][C:58]([O:61][CH2:62][CH3:63])([CH3:60])[CH3:59])=[CH:47][CH:46]=1.I([O-])(=O)(=O)=[O:66].[Na+]>>[CH3:1][S:2]([C:3]1[CH:4]=[CH:5][C:6]([O:9][CH2:10][CH2:11][CH:12]([CH3:21])[CH2:13][CH2:14][CH2:15][C:16]([O:19][CH3:20])([CH3:18])[CH3:17])=[CH:7][CH:8]=1)=[O:30].[CH3:43][S:44]([C:45]1[CH:50]=[CH:49][C:48]([O:51][CH2:52][CH:53]=[C:54]([CH3:64])[CH2:55][CH2:56][CH2:57][C:58]([O:61][CH3:62])([CH3:60])[CH3:59])=[CH:47][CH:46]=1)=[O:66].[CH3:43][S:44]([C:45]1[CH:46]=[CH:47][C:48]([O:51][CH2:52][CH2:53][CH:54]([CH3:64])[CH2:55][CH2:56][CH2:57][C:58]([O:61][CH2:62][CH3:63])([CH3:60])[CH3:59])=[CH:49][CH:50]=1)=[O:9].[CH3:43][S:44]([C:45]1[CH:46]=[CH:47][C:48]([O:51][CH2:52][CH:53]=[C:54]([CH3:64])[CH2:55][CH2:56][CH2:57][C:58]([O:61][CH2:62][CH3:63])([CH3:60])[CH3:59])=[CH:49][CH:50]=1)=[O:9]

Participants

8

Reactant 4

HCID 22749738HCID 22749738, compoundHCID 22749852HCID 22749852, compoundHCID 23667635Sodium periodateHCID 70608037HCID 70608037, compound

Product 4

HCID 22749858HCID 22749858, compoundHCID 22749883HCID 22749883, compoundHCID 70608252HCID 70608252, compoundHCID 70608772HCID 70608772, compound

Procedure

Each of 7-methoxy-3,7-dimethyloctyl 4-methylthiophenyl ether, 7-methoxy-3,7-dimethyloct-2-enyl 4-methylthiophenyl ether, 7-ethoxy-3,7-dimethyloctyl 4-methylthiophenyl ether and 7-ethoxy-3,7-dimethyloctyl-2-enyl 4-methylthiophenyl ether is treated with sodium metaperiodate according to the process of Example 6 to yield 7-methoxy-3,7-dimethyloctyl 4-methylsulfinylphenyl ether, 7-methoxy-3,7-dimethyloct-2-enyl 4-methylsulfinylphenyl ether, 7-ethoxy-3,7-dimethyloctyl 4-methylsulfinylphenyl ether and 7-ethoxy-3,7-dimethyloct-2-enyl 4-methylsulfinylphenyl ether, respectively. The corresponding 4-methylsulfonylphenyl ether are prepared using the process of Example 7.

Sources & evidence

ORD record
ord-ce1abcab2a1b4a55ba369e374f64295f
Source dataset
uspto-grants-1979_01
Patent number
US04137273

Reaction notes

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