Phosphate → Citrate phosphate

HRID 2164311Notes

Reaction equation

HRID 2164311 reaction equation
[P:1]([O-:5])([O-:4])([OH:3])=[O:2].[Na+].[Na+].P([O-])([O-])([O-])=O.O.[C:14]([OH:26])(=[O:25])[CH2:15][C:16]([CH2:21][C:22]([OH:24])=[O:23])([C:18]([OH:20])=[O:19])[OH:17]>O>[C:14]([O-:26])(=[O:25])[CH2:15][C:16]([CH2:21][C:22]([O-:24])=[O:23])([C:18]([O-:20])=[O:19])[OH:17].[P:1]([O-:5])([O-:4])([O-:3])=[O:2]

Participants

5

Reactant 3

HCID 1061PhosphateHCID 222302-Hydroxy-1,2,3-propanetricarboxylic acid hydrate (1:1)HCID 24203Sodium Phosphate, Dibasic

Product 1

HCID 21226156Citrate phosphate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent3×

Procedure

Reagent(ii) is a buffer prepared by first dissolving 144.8 grams (1.020 mol) of disodium hydrogen phosphate in 1.00 liter hot deionized water. The phosphate dissolved in the hot deionized water upon stirring. To this solution 102.95 grams (0.4902 mol) of citric acid monohydrate were added. The resulting solution was then diluted to 10.0 liters with additional deionized water, thus forming a citrate-phosphate solution, with a pH of 5.0.

Workup

  1. customa buffer prepared

Sources & evidence

ORD record
ord-cc48aca6ba6f405683162fde4197d482
Source dataset
uspto-grants-1985_03
Patent number
US04503143

Reaction notes

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