HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2164614Generated: November 2, 2026
Water → N,N-Dimethyl-N'-(6-allyloxybenzothiazole-2-sulfonyl)formamidine
https://huagongshe.com/reaction/2164614
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Allyl bromide | HCID 7841 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | N,N-Dimethyl-N'-(6-hydroxybenzothiazole-2-sulfonyl)formamidine | HCID 54375873 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | N,N-Dimethyl-N'-(6-allyloxybenzothiazole-2-sulfonyl)formamidine | HCID 53647804 | 70.7% |
Reaction Steps
A solution of product from Step A (1.14 gm, 4.0 mmol) and allyl bromide (0.5 mL, 5.5 mmol) in dimethyl sulfoxide (8 mL) containing potassium carbonate (0.75 gm, 5.4 mmol) was warmed at 60° C. for 15-20 hours. The reaction mixture was poured into water and the product was extracted into ethyl acetate, dried (Na2SO4) and evaporated to give a viscous oil (0.92 gm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04505923 |
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| Source dataset | uspto-grants-1985_03 |
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| ORD ID | ord-b236e1d2d20647fe8b9d12df24171e7a |
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| Source note | uspto-grants-1985_03 |
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