Thiophenol → HCID 178526135, compound

HRID 2164674Notes

Reaction equation

[C:1]1([S-])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+].[Na].C1([SH:16])C=CC=CC=1.[C:17]1([N:23]=[C:24]([OH:37])[C:25]2[C:26](=[C:30]([N+]([O-])=O)[CH:31]=[CH:32][CH:33]=2)[C:27]([OH:29])=O)[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>CS(C)=O.C(O)(=O)C.O.CO>[C:17]1([N:23]=[C:24]([OH:37])[C:25]2[C:26](=[CH:30][CH:31]=[CH:32][C:33]=2[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[C:27]([OH:29])=[S:16])[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1

Participants

Conditions

Temperature: 50 °C

Procedure

Dry sodium thiophenolate prepared from 7.5 g (0.33 gram equivalent) of sodium, 300 ml of methanol and 36 ml (0.33 mol) of thiophenol is dissolved in 300 ml of dimethylsulfoxide, and 80.4 g (0.3 mol) of 3-nitrophthalic acid N-phenylimide are added. The reaction mixture is heated at 50° C. for 90 minutes and then poured into a mixture of 300 ml of water and 300 ml of anhydrous acetic acid. The resulting suspension is filtered with suction and the product is dried at 80° C./13,000 Pa. 100 g (100% of theory) of 3-phenylthiophthalic acid N-phenylimide are obtained.

Workup

filtrationThe resulting suspension is filtered with suction
customthe product is dried at 80° C./13,000 Pa

Sources & evidence

ORD record: ord-16b591d963c14a0082ce5398657e6380
Source dataset: uspto-grants-1985_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04506083

Reaction notes

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