HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → HCID 13281343, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | Hydrazine hydrate (1:1) | HCID 24654 | — |
| Reactant | HCID 13281350 | HCID 13281350 | — |
| Solvent | Ethylene Glycol | HCID 174 | — |
| Product | HCID 13281343 | HCID 13281343 | 90.6% |
Reaction Steps
The reaction of 9-chloro-5,6,7,8-tetrahydrodibenzo[a,c]cycloocten-5-one (3.0 g, 0.015 mole), 85% hydrazine hydrate (4.5 g, 0.076 mole), potassium hydroxide (3.0 g, 0.046 mole) and ethylene glycol (39 ml) produced an oil. The oil was purified by column chromatography on silica gel, eluted with toluene to yield 4-chloro-5,6,7,8-tetrahydrodibenzo[a,c]cyclooctene as an oil (3.3 grams).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04507317 |
| Source dataset | uspto-grants-1985_03 |
| ORD ID | ord-e1083872b7e54aca91255755fa833b02 |
| Source note | uspto-grants-1985_03 |