HuagongsheHuagongshe Chemistry Print Report · For research reference only
(5-Methylpyrimidin-2-yl)methanol → 5-Methylpyrimidine-2-carbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (5-Methylpyrimidin-2-yl)methanol | HCID 23043337 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | 5-Methylpyrimidine-2-carbaldehyde | HCID 23043336 | — |
Reaction Steps
5-Methylpyrimidine-2-carboxaldehyde was prepared from 2-hydroxymethyl-5-methylpyrimidine by oxidation with excess manganese dioxide in boiling chloroform. The product was obtained as colourless crystals and was characterized by proton nuclear magnetic resonance spectroscopy. Proton nuclear magnetic resonance spectrum (CDCl3 ; δ in ppm): 2.44 (3H,s); 8.80 (2H,s); 10.06 (1H,s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04938793 |
| Source dataset | uspto-grants-1990_07 |
| ORD ID | ord-2bdf565a13fb4b56a4133264da693543 |
| Source note | uspto-grants-1990_07 |