HRID2165355

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID313

Hydrochloric Acid

ClH

$结构：CC1(C)[C@H](/C=C(\Cl)C(F)(F)F)[C@@H]1C(=O)O$

HCID11184106

(1S-cis)-Cyhalothric acid

C9H10ClF3O2

$结构：CC1(C)[C@@H](/C=C(\Cl)C(F)(F)F)[C@@H]1C(=O)O$

HCID12942379

未命名化合物

PRODUCTS

生成物

HCID156507

3-(2-Chloro-3,3,3-trifluoro-1-propen-1-yl)-2,2-dimethylcyclopropanecarboxylic acid

C9H10ClF3O2

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

The aqueous alkali phase was acidified with hydrochloric acid, and the precipitated product was isolated by extraction with methylene chloride, giving 341 g of a crystalline mass comprising 92 g of cis-3-(Z-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropanecarboxylic acid and 206 g of trans-3-(Z-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropanecarboxylic acid.

WORKUP

后处理

customgiving 341 g of a crystalline mass