Methyl propionate → Undec-1-en-1-ol

HRID 2165362Notes

Reaction equation

HRID 2165362 reaction equation
C[O:2][C:3](=O)[CH:4]=[CH:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].COC(=O)CC.[H][H]>CO>[CH:3]([OH:2])=[CH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

5

Reactant 3

HCID 11124Methyl propionateHCID 53793572HCID 53793572, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 44135745Undec-1-en-1-ol

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In about the same way as described under Example 2, an experiment was carried out with difference being that 10 ml methyl-undecenoate was included in the autoclave instead of 10 ml methylpropionate, while after 5 min hydrogen was added until a pressure increase of 30 bar was reached. The autoclave was kept at 80° C. for 5 hours giving a yield of 2.4 g methanol and about 1 g 1-undecenol.

Workup

  1. temperatureincrease of 30 bar

Sources & evidence

ORD record
ord-c7a6d286cf5845f1924c8c7357de989a
Source dataset
uspto-grants-1990_07
Patent number
US04939307

Reaction notes

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