2-Allylphenol → o-Allylphenol 1,3-bisglycidylresorcinol

HRID 2165447Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2165447
[CH2:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[OH:10])[CH:2]=[CH2:3].[CH2:11]([C:15]1([CH:22]=[CH:21][CH2:20][C:18]([CH2:23][CH:24]2[O:26][CH2:25]2)([OH:19])[CH2:17]1)[OH:16])[CH:12]1[O:14][CH2:13]1.[I-].C1(C(C2C=CC=CC=2)(C2C=CC=CC=2)C[PH3+])C=CC=CC=1.CC(O)C([O-])=O>>[CH2:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[OH:10])[CH:2]=[CH2:3].[CH2:23]([C:18]1([CH:20]=[CH:21][CH2:22][C:15]([CH2:11][CH:12]2[O:14][CH2:13]2)([OH:16])[CH2:17]1)[OH:19])[CH:24]1[O:26][CH2:25]1

Komponenten

5

Edukt 4

HCID 156242-AllylphenolHCID 91435LactateHCID 230447731,3-BisglycidylresorcinolHCID 66760890Triphenylethyl phosphonium iodide

Produkt 1

HCID 86742605o-Allylphenol 1,3-bisglycidylresorcinol

Reaktionsbedingungen

Temperatur
140 °C

Versuchsvorschrift

In a similar manner to that described in Example 1, o-allylphenol (134 g), 1,3-bisglycidylresorcinol (115.1 g), triphenylethylphosphonium iodide (0.75 g) and methylglycolate (145 g) were reacted at 100° C. for 13 hours. The solvent and excess o-allylphenol were removed by heating at 140° C. finally in vacuo. The yield of adduct was 227.9 g and it showed a viscocity of 280 mPa.s at 70° C.

Aufarbeitung

  1. customwere reacted at 100° C. for 13 hours
  2. customThe solvent and excess o-allylphenol were removed
  3. customat 70° C.

Quellen und Nachweise

ORD-Eintrag
ord-5486ac1a6a5f4f9fa0f82c7893b69a74
Quelldatensatz
uspto-grants-1990_07
Patentnummer
US04939305

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