Hydrochloric Acid → HCID 13920682, compound

HRID 2166166Notes

Reaction equation

HRID 2166166 reaction equation
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9]/[CH:10]=[CH:11]\[C:12]1[CH:17]=[CH:16][C:15]([NH:18][S:19]([CH3:22])(=[O:21])=[O:20])=[CH:14][CH:13]=1.[CH2:23]([NH2:30])[C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1.[ClH:31]>O>[ClH:31].[C:24]1([CH2:23][NH:30][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9]/[CH:10]=[CH:11]\[C:12]2[CH:17]=[CH:16][C:15]([NH:18][S:19]([CH3:22])(=[O:21])=[O:20])=[CH:14][CH:13]=2)[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 7504BenzylamineHCID 13920680HCID 13920680, compound

Product 1

HCID 13920682HCID 13920682, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

(Z)-N-[4-[3-[(6-Bromohexyl)oxy]-1-propenyl]phenyl]methanesulphonamide (2.0 g) was added to benzylamine (6 ml) at 125°, under nitrogen. The reaction mixture was stirred at 125° for 3 h, cooled to room temperature and added to 2N hydrochloric acid (50 ml) and water (20 ml). The resultant white solid was collected by filtration, washed in turn with 2N hydrochloric acid, water and ether then dried in vacuo at 50° to give the title compound as a white powder (1.0 g) m.p. 133°-134°.

Workup

  1. filtrationThe resultant white solid was collected by filtration
  2. washwashed in turn with 2N hydrochloric acid, water and ether
  3. customthen dried in vacuo at 50°

Sources & evidence

ORD record
ord-0c69b298180c411b926fd209df286dc1
Source dataset
uspto-grants-1990_07
Patent number
US04943591

Reaction notes

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