Trimethylamine → HCID 86744120, compound

HRID 2166444Notes

Reaction equation

HRID 2166444 reaction equation
[CH2:1]([O:17][CH2:18][C:19](=[CH2:31])[CH2:20][O:21][CH2:22][CH2:23][CH2:24][CH2:25][O:26][S:27]([CH3:30])(=[O:29])=[O:28])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH3:32][N:33]([CH3:35])[CH3:34]>C(O)C>[CH3:30][S:27]([O-:29])(=[O:28])=[O:26].[CH2:1]([O:17][CH2:18][C:19](=[CH2:31])[CH2:20][O:21][CH2:22][CH2:23][CH2:24][CH2:25][N+:33]([CH3:35])([CH3:34])[CH3:32])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 1146TrimethylamineHCID 23039617HCID 23039617, compound

Product 1

HCID 86744120HCID 86744120, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

1-Hexadecyloxy-3-[4-(methanesulfonyloxy)butoxy]-2-methylenepropane (from Preparation 7) (1.77 g) was refluxed with 33% trimethylamine in ethanol at 50° C. for 4 hours. Excess trimethylamine and ethanol were removed in vacuo. The product was recrystallized from chloroform/acetone.

Workup

  1. customExcess trimethylamine and ethanol were removed in vacuo
  2. customThe product was recrystallized from chloroform/acetone

Sources & evidence

ORD record
ord-a28bc141679e45c4b4e92aa61250a136
Source dataset
uspto-grants-1990_07
Patent number
US04945098

Reaction notes

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