HRID2166449

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID9256

Thiazole

C3H3NS

结构：C=C(COC(=O)CCCCCBr)COC(=O)NCCCCCCCCCCCCCCCCCC

HCID14064645

未命名化合物

PRODUCTS

生成物

结构：C=C(COC(=O)CCCCC[n+]1ccsc1)COC(=O)NCCCCCCCCCCCCCCCCCC.[Br-]

HCID67937581

未命名化合物

PROCEDURE

实验过程

1-Octadecylaminocarbonyloxy-3-(6-bromohexanoyloxy)-2-methylenepropane (from Preparation 9) (0.55 g) and thiazole (2.5 ml) were heated to 110° C. for 4 hours. The reaction mixture was evaporated to dryness in vacuo.

WORKUP

后处理

customThe reaction mixture was evaporated to dryness in vacuo

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e07475132f504da3b608ac0f62298f9e
来源数据集: uspto-grants-1990_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04945098
来源说明: uspto-grants-1990_07

反应 SMILES

[CH2:1]([NH:19][C:20]([O:22][CH2:23][C:24](=[CH2:35])[CH2:25][O:26][C:27](=[O:34])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][Br:33])=[O:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[S:36]1[CH:40]=[CH:39][N:38]=[CH:37]1>>[Br-:33].[CH2:1]([NH:19][C:20]([O:22][CH2:23][C:24](=[CH2:35])[CH2:25][O:26][C:27](=[O:34])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][N+:38]1[CH:39]=[CH:40][S:36][CH:37]=1)=[O:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]