Carbon Disulfide → HCID 20497544, compound

HRID 2166937Notes

Reaction equation

HRID 2166937 reaction equation
[CH2:1]([NH:4][CH2:5][CH2:6][NH2:7])[CH:2]=[CH2:3].[C:8](=[S:10])=[S:9]>C(O)C>[CH2:1]([NH:4][CH2:5][CH2:6][NH:7][C:8](=[S:9])[SH:10])[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 6348Carbon DisulfideHCID 520997N-Allylethylenediamine

Product 1

HCID 20497544HCID 20497544, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Conditions

Temperature
5 °C

Procedure

To 10 g of N-allylethylendiamine (0.1 moles) dissolved in 50 cc of ethanol there were admixed, under stirring, 7.6 g of CS2 (0.1 moles) dissolved in 50 cc ethanol, the temperature being maintained at about 5° C. Once the addition is accomplished, stirring is continued for another 15 minutes, after which the resulting precipitate is filtered and, after washing with ethanol, consists of 15.6 g of white crystals having a m.p. of 125° C. (with decomposition) of N-(2'-allylaminoethyl)dithiocarbamic acid having the following structure of an internal salt: ##STR20##

Workup

  1. additionOnce the addition
  2. stirringstirring
  3. filtrationafter which the resulting precipitate is filtered
  4. washafter washing with ethanol

Sources & evidence

ORD record
ord-0dc1f16b9f1246a2aeb98e2b5c97cc10
Source dataset
uspto-grants-1983_06
Patent number
US04390705

Reaction notes

Loading…