3-Carboxybenzaldehyde → HCID 62925667, compound

HRID 2170848Notes

Reaction equation

HRID 2170848 reaction equation
[CH:1]([C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][CH:11]=1)[C:6]([OH:8])=[O:7])=O.[CH3:12][NH:13][C:14]1[C:15]([NH2:20])=[CH:16][CH:17]=[CH:18][CH:19]=1>>[CH3:12][N:13]1[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=2[N:20]=[C:1]1[C:3]1[CH:4]=[C:5]([CH:9]=[CH:10][CH:11]=1)[C:6]([OH:8])=[O:7]

Participants

3

Reactant 2

HCID 120773-CarboxybenzaldehydeHCID 78498N-Methyl-o-phenylenediamine

Product 1

HCID 62925667HCID 62925667, compoundYield 51%

Procedure

The title compound was prepared in 51% yield (428 g, a slight brown solid) from 3-formylbenzoic acid (500 mg, 3.33 mmol) and N1-methylbenzene-1,2-diamine (407 mg, 3.33 mmol) by the similar manner in Intermediate-7.

Sources & evidence

ORD record
ord-64840ed48c61423492c755fb1ca6eb35
Source dataset
uspto-grants-2015_06
Patent number
US09051296B2

Reaction notes

Loading…