Iodoethane → HCID 67811529, compound

HRID 2172544Notes

Reaction equation

HRID 2172544 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9]2[CH2:14][CH2:13][CH2:12][C:11](=O)[CH:10]=2)=[CH:4][CH:3]=1.COC1C=CC(P2(SP(C3C=CC(OC)=CC=3)(=S)S2)=[S:25])=CC=1.[CH2:38](I)[CH3:39]>>[CH2:38]([S:25][C:11]1[CH2:12][CH2:13][CH2:14][C:9](=[N:8][C:5]2[CH:6]=[CH:7][C:2]([CH3:1])=[CH:3][CH:4]=2)[CH:10]=1)[CH3:39]

Participants

4

Reactant 3

HCID 6340IodoethaneHCID 87949Lawesson's reagentHCID 27486243-[(4-Methylphenyl)amino]-2-cyclohexen-1-one

Product 1

HCID 67811529HCID 67811529, compound

Procedure

N-[3-(Ethylsulphanyl)cyclohex-2-en-1-ylidene]-4-methylaniline is prepared from 3-[(4-methyl-phenyl)amino]cyclohex-2-en-1-one by reaction with Lawesson reagent and subsequent alkylation with ethyl iodide analogously to J. Org. Chem. 1984, 49, 3314.

Sources & evidence

ORD record
ord-cc50bfb5d80a4c3697c264aefeb10040
Source dataset
uspto-grants-2015_06
Patent number
US09055743B2

Reaction notes

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