HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-nitro-N-phenylpyridin-4-amine → 4-N-phenylpyridine-3,4-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-nitro-N-phenylpyridin-4-amine | HCID 612005 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 4-N-phenylpyridine-3,4-diamine | HCID 10583675 | 100% |
Reaction Steps
To a solution of 3-nitro-N-phenylpyridin-4-amine (20 g, 93 mmol) in MeOH (500 mL) was added 10% Pd/C. The reaction was stirred under a hydrogen atmosphere for 10 h. The reaction was filtered and the filtrate was concentrated to afford the product (17.2 g, 100%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09066946B2 |
| Source dataset | uspto-grants-2015_06 |
| ORD ID | ord-049b9071bff5482da69b7e67d82ec15a |
| Source note | uspto-grants-2015_06 |