1,3-Benzenedimethanamine → HCID 86593943, compound

HRID 2181734Notes

Reaction equation

HRID 2181734 reaction equation
[O:1]=[C:2]([OH:14])[C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([C:11]([OH:13])=[O:12])[OH:10])[OH:8])[OH:6])[OH:4].[C:15]1([CH2:23][NH2:24])[CH:20]=[CH:19][CH:18]=[C:17]([CH2:21][NH2:22])[CH:16]=1>O>[O:1]=[C:2]([O-:14])[C@@H:3]([C@H:5]([C@H:7]([C@@H:9]([C:11]([O-:13])=[O:12])[OH:10])[OH:8])[OH:6])[OH:4].[C:15]1([CH2:23][NH3+:24])[CH:20]=[CH:19][CH:18]=[C:17]([CH2:21][NH3+:22])[CH:16]=1

Participants

4

Reactant 2

HCID 151331,3-BenzenedimethanamineHCID 3037582Galactaric acid

Product 1

HCID 86593943HCID 86593943, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
70 °C

Procedure

To a stirred suspension of galactaric acid (5.004 g, 23.811 mmol) in deionized water (50.0 mL), m-xylylenediamine (3.15 mL, 23.868 mmol) was added using a pipette. The reaction mixture was stirred at 70° C. for 16 h. The reaction mixture was filtered, washed with several small portions of deionized water, and then dried under vacuum at room temperature for 24 h to give white solid, m-xylylenediammonium galactarate 14, 6.016 g, 17.372 mmol, 72.88%).

Workup

  1. additionwas added
  2. filtrationThe reaction mixture was filtered
  3. washwashed with several small portions of deionized water
  4. customdried under vacuum at room temperature for 24 h

Sources & evidence

ORD record
ord-abf6e97555554f0f9226a421db73d1f6
Source dataset
uspto-grants-2005_05
Patent number
US06894135B2

Reaction notes

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