Resorcinol → 2-(2,4-Dihydroxyphenyl)-4,6-bis(3,4-dimethylphenyl)-1,3,5-triazine

HRID 2184425Notes

Reaction equation

HRID 2184425 reaction equation
[C:1]1([CH:8]=[CH:7][CH:6]=[C:4]([OH:5])[CH:3]=1)[OH:2].Cl[C:10]1[N:15]=[C:14]([C:16]2[CH:21]=[CH:20][C:19]([CH3:22])=[C:18]([CH3:23])[CH:17]=2)[N:13]=[C:12]([C:24]2[CH:29]=[CH:28][C:27]([CH3:30])=[C:26]([CH3:31])[CH:25]=2)[N:11]=1>>[OH:2][C:1]1[CH:3]=[C:4]([OH:5])[CH:6]=[CH:7][C:8]=1[C:10]1[N:15]=[C:14]([C:16]2[CH:21]=[CH:20][C:19]([CH3:22])=[C:18]([CH3:23])[CH:17]=2)[N:13]=[C:12]([C:24]2[CH:29]=[CH:28][C:27]([CH3:30])=[C:26]([CH3:31])[CH:25]=2)[N:11]=1

Participants

3

Reactant 2

HCID 5054ResorcinolHCID 224759902-Chloro-4,6-bis(3,4-dimethylphenyl)-1,3,5-triazine

Product 1

HCID 1358045052-(2,4-Dihydroxyphenyl)-4,6-bis(3,4-dimethylphenyl)-1,3,5-triazineYield 83%

Conditions

Temperature
80 °C

Procedure

To the above reaction mixture was added 1.1 eq of resorcinol and the mixture was heated to 80° C. Within 2 h, an HPLC analysis indicated 2-chloro-4,6-bis(3,4-dimethylphenyl)-1,3,5-triazine and its isomer had completely reacted to form 83% of 2-(2,4-dihydroxyphenyl)-4,6-bis(3,4-dimethylphenyl)-1,3,5-triazine and 6% of its isomer.

Workup

  1. customhad completely reacted

Sources & evidence

ORD record
ord-e5456088b1fc46a7a2dc506398fe5272
Source dataset
uspto-grants-2005_05
Patent number
US06900314B2

Reaction notes

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