HCID 73886677, compound → HCID 22451293, compound

HRID 2185692Notes

Reaction equation

HRID 2185692 reaction equation
[N:1]([C:4](=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[C:13]([O:17][CH3:18])[C:12]=1[O:19][CH3:20])[C:5]([O:7][CH2:8][CH3:9])=[O:6])=[N+]=[N-]>C1(C)C=CC=CC=1>[CH3:20][O:19][C:12]1[C:13]([O:17][CH3:18])=[CH:14][CH:15]=[C:16]2[C:11]=1[CH:10]=[C:4]([C:5]([O:7][CH2:8][CH3:9])=[O:6])[NH:1]2

Participants

3

Reactant 1

HCID 73886677HCID 73886677, compound

Product 1

HCID 22451293HCID 22451293, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Ethyl 2-azido-3-(2,3-dimethoxyphenyl)propeneoate (4.0 g, 144 mmol) was suspended in toluene (120 ml) and the mixture was refluxed for three hours and then cooled and stirred at room temperature overnight. The solids were collected by filtration in order to give the product in the form of a yellow solid.

Workup

  1. temperaturethe mixture was refluxed for three hours
  2. temperaturecooled
  3. filtrationThe solids were collected by filtration in order
  4. customto give the product in the form of a yellow solid

Sources & evidence

ORD record
ord-a359b80643df44f9b54ebc4c8ebaf0c9
Source dataset
uspto-grants-2002_06
Patent number
US06403561B1

Reaction notes

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