HCID 69892168, compound → HCID 86586189, compound

HRID 2186279Notes

Reaction equation

HRID 2186279 reaction equation
[C:1]([C:5]1[C:19]([O:20]CC(C)=C)=[CH:18][C:8]2[CH2:9][C:10]3([O:17][C:7]=2[CH:6]=1)[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]3)([CH3:4])([CH3:3])[CH3:2]>CN(C)C1C=CC=CC=1>[C:1]([C:5]1[C:19]([OH:20])=[C:18]([CH2:3][C:1]([CH3:4])=[CH2:2])[C:8]2[CH2:9][C:10]3([O:17][C:7]=2[CH:6]=1)[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]3)([CH3:2])([CH3:3])[CH3:4]

Participants

3

Reactant 1

HCID 69892168HCID 69892168, compound

Product 1

HCID 86586189HCID 86586189, compoundYield 179.8%

Reagents, catalysts & solvents 1

HCID 949N,N-DimethylanilineSolvent

Procedure

0.89 g of 6-t-butyl-5-(2-methyl-2-propenyloxy)-2,3-dihydrobenzofuran-2-spiro-1′-cycloheptane was dissolved in 3 ml of dimethylaniline and the solution was treated in the same manner as in Example 8-2) to give 0.80 g of 6-t-butyl-5-hydroxy-4-(2-methyl-2-propenyl)-2,3-dihydrobenzofuran-2-spiro-1′-cycloheptane as a colorless oil (yield 90%).

Workup

  1. additionthe solution was treated in the same manner as in Example 8-2)

Sources & evidence

ORD record
ord-a93e7c2cb3a64fc68c3eecc684e761aa
Source dataset
uspto-grants-2002_06
Patent number
US06403639B1

Reaction notes

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