2,5-Dimethylfuran → 2,5-Furandimethanol

HRID 2190895Notes

Reaction equation

HRID 2190895 reaction equation
CC1OC(C)=CC=1.[OH:8][CH2:9][C:10]1[O:16][C:13]([CH:14]=[O:15])=[CH:12][CH:11]=1>>[OH:15][CH2:14][C:13]1[O:16][C:10]([CH2:9][OH:8])=[CH:11][CH:12]=1

Participants

3

Reactant 2

HCID 122662,5-DimethylfuranHCID 2373325-(Hydroxymethyl)furfural

Product 1

HCID 746632,5-Furandimethanol

Procedure

In another aspect, the present disclosure provides a method C for preparing 2,5-dimethylfuran, which includes the steps of: a) combining 5-(hydroxymethyl)furfural (HMF) with H2, a first catalyst, and an aprotic solvent; b) reacting the mixture of step (a) to form 2,5-bis(hydroxymethyl)furan (BHMF); c) adding a carboxylic acid, and a second catalyst to the reaction mixture of step (b) to form an ester of BHMF; and d) adding H2 to the reaction mixture that includes the ester of BHMF of step (c) to form 2,5-dimethylfuran.

Workup

  1. customIn another aspect, the present disclosure provides a method C

Sources & evidence

ORD record
ord-7b6d076b65a64f339fe534a6c8d1f7c2
Source dataset
uspto-grants-2012_12
Patent number
US08324409B2

Reaction notes

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