Cyclohexanol → HCID 67523722, compound

HRID 2190943Notes

Reaction equation

HRID 2190943 reaction equation
[OH:1][C:2]1[CH:14]=[CH:13][C:5]2[C:6](=[O:12])[O:7][C:8]([CH3:11])([CH3:10])[O:9][C:4]=2[CH:3]=1.[CH:15]1(O)[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1>>[CH:15]1([O:1][C:2]2[CH:14]=[CH:13][C:5]3[C:6](=[O:12])[O:7][C:8]([CH3:10])([CH3:11])[O:9][C:4]=3[CH:3]=2)[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1

Participants

3

Reactant 2

HCID 7966CyclohexanolHCID 105839507-hydroxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

Product 1

HCID 67523722HCID 67523722, compound

Procedure

7-Cyclohexyloxy-2,2-dimethyl-benzo[1,3]dioxin-4-one was prepared from 7-hydroxy-2,2-dimethyl-benzo[1,3]dioxin-4-one and cyclohexanol under conditions analogous to example 51-a. 1H NMR (200 MHz, CDCl3): δ (ppm)=7.82 (d, J=8.8 Hz, 1H), 6.61 (dd, J=8.8, 2.4 Hz, 1H), 6.39 (d, J=2.0 Hz, 1H), 4.30 (m, 1H), 2.02-1.28 (m, 10H), 1.73 (s, 6H).

Sources & evidence

ORD record
ord-0241619e802149959d7f77a1a79d4048
Source dataset
uspto-grants-2012_12
Patent number
US08324405B2

Reaction notes

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