Carbon Dioxide → Methanesulfonic acid, copper(2+) salt (2:1)

HRID 2194321Notes

Reaction equation

HRID 2194321 reaction equation
C(=O)([O-])[O-].[Cu+2:5].[CH3:6][S:7]([OH:10])(=[O:9])=[O:8].C(=O)=O>O>[CH3:6][S:7]([O-:10])(=[O:9])=[O:8].[Cu+2:5].[CH3:6][S:7]([O-:10])(=[O:9])=[O:8]

Participants

5

Reactant 3

HCID 280Carbon DioxideHCID 6395Methanesulfonic AcidHCID 14452Copper carbonate2×

Product 1

HCID 11196097Methanesulfonic acid, copper(2+) salt (2:1)

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

190 g copper carbonate was introduced into approximately 0.7 L ion-exchanged water. The solution was stirred and converted into a slurry and methanesulfonic acid was then added in small portions. The copper carbonate underwent dissolution with the production of carbon dioxide and finally underwent complete dissolution to yield an aqueous copper methanesulfonate solution having a copper concentration of 100 g/L. The pH of the obtained aqueous copper methanesulfonate solution was 2.9.

Workup

  1. additionwas then added in small portions

Sources & evidence

ORD record
ord-57ab4249255a4f368978e9ca7bd04157
Source dataset
uspto-grants-2012_12
Patent number
US08333834B2

Reaction notes

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