HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Oxygen
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Propylene | HCID 8252 | — |
| Reactant | Mycophenolic acid glucuronide | HCID 6442661 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Water | HCID 962 | — |
| Product | Oxygen | HCID 977 | — |
| Product | Propylene | HCID 8252 | — |
| Product | Allyl acetate | HCID 11584 | — |
Reaction Steps
After uniformly diluting 14.0 ml of each of catalysts B and G-I obtained in Examples 2, 5 and 6 and Comparative Example 3 with 42.0 ml of silica carrier, it was packed into a reaction tube (SUS316 L, inner diameter: 25 mm). Gas with a gas composition of propylene:oxygen:acetic acid:water in a volume ratio of 29:6:7.1:19:38.9 was introduced at a space velocity of 2070 h−1 with a reaction temperature of 135° C. and a reaction pressure of 0.8 MPaG (gauge pressure), for reaction to obtain allyl acetate from propylene, oxygen and acetic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08338327B2 |
| Source dataset | uspto-grants-2012_12 |
| ORD ID | ord-29fe78e18a7f4b1c93e9f2419ba10209 |
| Source note | uspto-grants-2012_12 |