Ethanol → HCID 178526054, compound

HRID 2197254Notes

Reaction equation

HRID 2197254 reaction equation
[C:1]([O:5][C:6]([C:9]([C:12]([O:15][CH:16]([C:18]([C:21]([O:23]C)=[O:22])([F:20])[F:19])[F:17])([F:14])[F:13])([F:11])[F:10])([F:8])[F:7])([F:4])([F:3])[F:2].C(O)C.[OH-].[K+:29]>O>[C:1]([O:5][C:6]([C:9]([C:12]([O:15][CH:16]([C:18]([C:21]([O:23][K:29])=[O:22])([F:20])[F:19])[F:17])([F:14])[F:13])([F:11])[F:10])([F:8])[F:7])([F:4])([F:3])[F:2]

Participants

5

Reactant 3

HCID 702EthanolHCID 14797Potassium HydroxideHCID 131727912Methyl 2,2,3-trifluoro-3-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]propanoate

Product 1

HCID 178526054HCID 178526054, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
40 °C

Procedure

CF3O(CF2)3OCHFCF2COOCH3 (19.6 grams, 50.0 mmol), 15 grams of ethanol, 2.8 grams (50 mmol) of potassium hydroxide, and 2 grams of water were added to a 100-mL, 3-necked flask, equipped with a stirrer, a condenser, and a thermometer. The reaction mixture was heated on a heating mantle and stirred for 6 hours at 40° C. A clear, colorless solution of CF3O(CF2)3OCHFCF2COOK was obtained.

Workup

  1. customequipped with a stirrer, a condenser
  2. temperatureThe reaction mixture was heated on a heating mantle

Sources & evidence

ORD record
ord-cb6670db64704119867dca3447ffe5a1
Source dataset
uspto-grants-2012_12
Patent number
US08338517B2

Reaction notes

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