Dimethyl Sulfoxide → HCID 86648446, compound

HRID 2198014Notes

Reaction equation

[Cl:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=O)=[CH:4][CH:3]=1.[CH3:10][S:11]([CH3:13])=[O:12]>>[Cl:1][C:2]1[CH:9]=[CH:8][C:5]([CH3:6])=[CH:4][CH:3]=1.[CH3:5][C:4]1[CH:3]=[CH:2][CH:9]=[CH:8][C:10]=1[S:11]([C:13]1[CH:2]=[CH:9][CH:8]=[CH:5][C:4]=1[CH3:3])=[O:12]

Participants

Reactant 2

HCID 679Dimethyl Sulfoxide

HCID 77264-Chlorobenzaldehyde

Product 1

HCID 86648446HCID 86648446, compound

Procedure

The yield of p-chlorobenzaldehyde is 58%. Compared with the reaction with DMSO as sulphoxide, the yield is thus higher by a factor of 1.53. The difference between the ionisation potentials is only 0.1 eV in this case.

Sources & evidence

ORD record: ord-edcf109529cd491a9b49b3204ff561f1
Source dataset: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08338649B2

Reaction notes

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