Dimethyl Sulfoxide → HCID 86648447, compound

HRID 2198015Notes

Reaction equation

[Cl:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=O)=[CH:4][CH:3]=1.[CH3:10][S:11]([CH3:13])=[O:12]>>[Cl:1][C:2]1[CH:9]=[CH:8][C:5]([CH3:6])=[CH:4][CH:3]=1.[Cl:1][C:2]1[CH:9]=[CH:8][C:10]([S:11]([C:13]2[CH:4]=[CH:3][C:2]([Cl:1])=[CH:9][CH:8]=2)=[O:12])=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 679Dimethyl Sulfoxide

HCID 77264-Chlorobenzaldehyde

Product 1

HCID 86648447HCID 86648447, compound

Procedure

The yield of p-chlorobenzaldehyde is 50%. Compared with the reaction with DMSO as sulphoxide, the yield is thus higher by a factor of 1.32. The difference between the ionisation potentials is 0.2 eV in this case.

Sources & evidence

ORD record: ord-d47164715d4a4436b1bd3c7da5a2c95a
Source dataset: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08338649B2

Reaction notes

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