Dimethyl Sulfoxide → HCID 86648448, compound

HRID 2198016Notes

Reaction equation

[Br:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=O)=[CH:4][CH:3]=1.[CH3:10][S:11]([CH3:13])=[O:12]>>[Br:1][C:2]1[CH:9]=[CH:8][C:5]([CH3:6])=[CH:4][CH:3]=1.[C:10]1([S:11]([C:13]2[CH:6]=[CH:5][CH:8]=[CH:9][CH:2]=2)=[O:12])[CH:8]=[CH:9][CH:2]=[CH:3][CH:4]=1

Participants

Reactant 2

HCID 679Dimethyl Sulfoxide

HCID 707414-Bromobenzaldehyde

Product 1

HCID 86648448HCID 86648448, compound

Procedure

The yield of p-bromobenzaldehyde is 66%. Compared with the reaction with DMSO as sulphoxide, the yield is thus higher by a factor of 1.94. The difference between the ionisation potentials is 0.2 eV in this case.

Sources & evidence

ORD record: ord-f619ef74012349daa5c2c90b20bce464
Source dataset: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08338649B2

Reaction notes

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