HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → Diethyl 2-amino-13-carboxy-1,14-tetradecanedicarboxylate hydrochloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Diethyl 2-t-butoxycarbonylamino-13-carboxy-1,14-tetradecanedicarboxylate | HCID 19930832 | — |
| Product | Diethyl 2-amino-13-carboxy-1,14-tetradecanedicarboxylate hydrochloride | HCID 19930814 | — |
Reaction Steps
Diethyl 2-t-butoxycarbonylamino-13-carboxy-1,14-tetradecanedicarboxylate (3.98 g, 8.40 mmol) is dissolved in methylene chloride (150.0 mL), and hydrogen chloride gas is bubbled through the solution for 15 minutes. The sealed reaction is stirred for 2.5 hours, and then the solvent is evaporated to give diethyl 2-amino-13-carboxy-1,14-tetradecanedicarboxylate hydrochloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05426103 |
| Source dataset | uspto-grants-1995_06 |
| ORD ID | ord-7ec1e5eaddb34ae79356893060a4661b |
| Source note | uspto-grants-1995_06 |