Hydrogen Peroxide → HCID 13075706, compound

HRID 2198543Notes

Reaction equation

[F:1][C:2]([F:35])([F:34])[C:3]([OH:33])([CH2:8][CH2:9][CH2:10][C@H:11]([C@@H:13]1[C@:30]2([CH3:31])[C@H:16]([C@H:17]3[C@H:27]([CH2:28][CH2:29]2)[C@:25]2([CH3:26])[C:20](=[CH:21][C:22](=[O:32])[CH:23]=[CH:24]2)[CH:19]=[CH:18]3)[CH2:15][CH2:14]1)[CH3:12])[C:4]([F:7])([F:6])[F:5].[OH:36]O>>[F:1][C:2]([F:34])([F:35])[C:3]([OH:33])([CH2:8][CH2:9][CH2:10][C@H:11]([C@@H:13]1[C@:30]2([CH3:31])[C@H:16]([C@H:17]3[C@H:27]([CH2:28][CH2:29]2)[C@:25]2([CH3:26])[C:20](=[CH:21][C:22](=[O:32])[C@@H:23]4[O:36][C@@H:24]42)[CH:19]=[CH:18]3)[CH2:15][CH2:14]1)[CH3:12])[C:4]([F:6])([F:5])[F:7]

Participants

Reactant 2

HCID 784Hydrogen Peroxide

HCID 13075704HCID 13075704, compound

Product 1

HCID 13075706HCID 13075706, compound

Procedure

treating the resulting 26,26,26,27,27,27-hexafluoro-25-hydroxycholest-1,4,6-trien-3-one with hydrogen peroxide to obtain 26,26,26,27,27,27-hexafluoro-25-hydroxy-1α,2α-epoxycholest-4,6-dien-3-one

Sources & evidence

ORD record: ord-a82c5bd98a88411ba94fa518300792c8
Source dataset: uspto-grants-1982_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04358406

Reaction notes

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