Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methylhydrazine | HCID 6061 | — |
| Reactant | 3-Bromopyridine-2-carbaldehyde | HCID 16414231 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 117696427 | HCID 117696427 | 99.1% |
Reaction Steps
3-bromo-2-formylpyridine (5 g, 26.88 mmol) and methylhydrazine (1.70 mL, 32.25 mmol) are dissolved in ethanol (10 mL) and heated at 80° C. for 2 h. Volatiles are removed under reduced pressure and the residue is re-evaporated several times to give N-[1-(3-Bromo-pyridin-2-yl)-methylidene]-N′-methyl-hydrazine (5.70 g, 99%)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09371282B2 |
|---|
| Source dataset | uspto-grants-2016_06 |
|---|
| ORD ID | ord-e2b97b71ee764e5baf9a056f0dbbd852 |
|---|
| Source note | uspto-grants-2016_06 |
|---|
