HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannane, tributyl(1-ethoxyethenyl)- → 2-[(3-Acetyl-4-pyridyl)methyl]-6,7-dimethoxy-tetralin-1-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannane, tributyl(1-ethoxyethenyl)- | HCID 619414 | — |
| Reactant | 2-[(3-Bromo-4-pyridyl)methyl]-6,7-dimethoxy-tetralin-1-one | HCID 118557859 | — |
| Product | 2-[(3-Acetyl-4-pyridyl)methyl]-6,7-dimethoxy-tetralin-1-one | HCID 118558021 | — |
Reaction Steps
The title compound 104 is prepared according to the procedure reported in Example 36.5 with compound 100 (175 mg, 0.47 mmol) and (l-ethoxyvinyl)tri(n-butyl)stannane (0.16 mL, 0.47 mmol) as reactants. White solid. (Yield 93.2 g, 58%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09376387B2 |
| Source dataset | uspto-grants-2016_06 |
| ORD ID | ord-7c7b1159ce414e74aee2b51b9f3c8cf5 |
| Source note | uspto-grants-2016_06 |