Nitrogen → HCID 69192170, compound

HRID 2209142Notes

Reaction equation

HRID 2209142 reaction equation
N#N.[I:3][C:4]1[CH:8]=[CH:7][NH:6][N:5]=1.[CH3:9][C:10](O)([CH3:12])[CH3:11].S(=O)(=O)(O)O>>[C:10]([N:6]1[CH:7]=[CH:8][C:4]([I:3])=[N:5]1)([CH3:12])([CH3:11])[CH3:9]

Participants

5

Reactant 4

HCID 947NitrogenHCID 1118Sulfuric AcidHCID 6386tert-ButanolHCID 178506555HCID 178506555, compound

Product 1

HCID 69192170HCID 69192170, compound

Conditions

Temperature
100 °C

Procedure

To a round-bottomed flask equipped with a stifling bar and a N2 tee, 3-iodo-1H-pyrazole (2.00 g, 10 mmol), 2-methylpropan-2-ol (7.64 g, 103 mmol), and concentrated sulfuric acid (1.08 g, 11 mmol) were added. The resulting mixture was heated at 100° C. for 3 hrs.

Workup

  1. customTo a round-bottomed flask equipped with a stifling bar

Sources & evidence

ORD record
ord-a52d6ee2cc434c839e13d7d5ff9fb197
Source dataset
uspto-grants-2016_06
Patent number
US09376441B2

Reaction notes

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