Acetic Acid → HCID 572634, compound

HRID 2211327Notes

Reaction equation

HRID 2211327 reaction equation
S(=O)(=O)(O)O.C[C:7]1([OH:14])[CH2:12][CH:11]2[CH2:13][CH:8]1[CH2:9][CH2:10]2.[C:15]([OH:18])(=O)[CH3:16].[C:19](=O)([O-])[O-].[Na+].[Na+]>O>[C:15]([O:14][CH:7]1[CH2:12][CH:11]2[CH2:13][C:8]1([CH3:19])[CH2:9][CH2:10]2)(=[O:18])[CH3:16]

Participants

6

Reactant 4

HCID 176Acetic AcidHCID 1118Sulfuric AcidHCID 10340Sodium CarbonateHCID 2969202-Methylbicyclo[2.2.1]heptan-2-ol

Product 1

HCID 572634HCID 572634, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
60 °C

Procedure

1 ml of 75% sulfuric acid was added to 240.0 g (1.9M) of the alcohol (II) obtained in 1--1) above and 500 ml of glacial acetic acid and the resulting mixture was stirred at 60° C. for three hours. After cooling, the reaction mixture was diluted with 3 l of water and then neutralized with sodium carbonate.

Workup

  1. temperatureAfter cooling

Sources & evidence

ORD record
ord-c74bf94504904731bfa5875474d495e7
Source dataset
uspto-grants-1995_10
Patent number
US05463118

Reaction notes

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