HCID 131725926, compound → Bis(eta-cyclopentadienyl) iron
Reaction equation
[CH2:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11].[CH-]1C=CC=C1.[CH-]1C=CC=C1.[Fe+2]>F[P-](F)(F)(F)(F)F.C([N+](CCCC)(CCCC)CCCC)CCC>[CH-:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.[CH-:6]1[CH:10]=[CH:9][CH:8]=[CH:7]1.[Fe+2:11]Participants
3
Reagents, catalysts & solvents 1
Procedure
Ru3+/2+ and Ru(bpy2)(bpy')0/*−]2+ couples for compounds (a), (b), (c), and (e) were recorded and corrected for the junction potential using ferrocenium/ferrocene as an internal standard. In the cell, CV of 0.05 mM ferrocene solution in 0.1 M tetrabutylammonium hexafluorophosphate gave E0(Fc+/Fc)=498 mV vs. SCE. Junction potentials in acetonitrile were found to be 191 mV.
Sources & evidence
- ORD record
- ord-2449a8689d41402c99ae9fa038bd4a89
- Source dataset
- uspto-grants-2006_09
- Patent number
- US07105310B1
Reaction notes
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