HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 4-methoxyacetoacetate → HCID 45117070, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 4-methoxyacetoacetate | HCID 123500 | — |
| Reactant | 4-Fluoro-N-hydroxybenzimidoyl chloride | HCID 5706360 | — |
| Product | HCID 45117070 | HCID 45117070 | 74% |
Reaction Steps
As described for Example 36c, (E)- and/or (Z)-N-hydroxy-4-fluoro-benzenecarboximidoyl chloride (12.1 g, 70 mmol) was converted, using 4-methoxy-3-oxo-butyric acid methyl ester instead of acetylacetone to the title compound (13.8 g, 74%) which was obtained as a light yellow solid. MS: m/e=266.0 [M+H]+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07414061B2 |
| Source dataset | uspto-grants-2008_08 |
| ORD ID | ord-3776d238d9fb4b8b952e6dc0922ac95e |
| Source note | uspto-grants-2008_08 |