Methyl Acrylate → HCID 86605946, compound

HRID 2220024Notes

Reaction equation

HRID 2220024 reaction equation
[C:1](=[C:4]([OH:15])[C@@H:5]([OH:14])[C@H:6]1[O:11][CH:9]([OH:10])[C@H:8]([OH:12])[C@H:7]1[OH:13])([CH3:3])[CH3:2].[C:16]([O:20][CH3:21])(=[O:19])[CH:17]=[CH2:18]>>[C:1](=[C:4]([OH:15])[C@@H:5]([OH:14])[C@H:6]1[O:11][CH:9]([OH:10])[C@H:8]([OH:12])[C@H:7]1[OH:13])([CH3:3])[CH3:2].[C:16]([O:20][CH3:21])(=[O:19])[CH:17]=[CH2:18]

Participants

3

Reactant 2

HCID 7294Methyl AcrylateHCID 69082566HCID 69082566, compound

Product 1

HCID 86605946HCID 86605946, compound

Procedure

5 mmol of isopropylidene-glucofuranose (IP-Glu), 50 mmol of methyl acrylate (MA), optionally 1.0 g of molecular sieve (5 Å), optionally 10 ml of solvent, and 100 mg of Novozym 435 were shaken at 40° C. for 24 h.

Sources & evidence

ORD record
ord-14da18ccc3634796b21e75adb1a6284b
Source dataset
uspto-grants-2008_08
Patent number
US07416867B2

Reaction notes

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