HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methoxycyclohexanol (cis,trans) → 4-Methoxycyclohexanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methoxycyclohexanol (cis,trans) | HCID 140332 | — |
| Reactant | Alumina | HCID 9989226 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4-Methoxycyclohexanone | HCID 535028 | — |
Reaction Steps
A solution of 4.2 g 4-methoxycyclohexanol in 30 ml dichloromethane is added to a suspension of 52.6 g pyridinium chlorochromate on basic aluminium oxide in 90 ml dichloromethane. The suspension is stirred for 3 h at ambient temperature. Then the mixture is filtered through silica gel (dichloromethane) and the solvent is eliminated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07417032B2 |
| Source dataset | uspto-grants-2008_08 |
| ORD ID | ord-2d832d0e2c544a72aa0bb16ba7489bac |
| Source note | uspto-grants-2008_08 |