HuagongsheHuagongshe Chemistry Print Report · For research reference only
Caprolactam → HCID 69215353, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Caprolactam | HCID 7768 | — |
| Reactant | (Isocyanatomethyl)(methoxy)dimethylsilane | HCID 71360899 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 69215353 | HCID 69215353 | — |
Reaction Steps
A solution of 1.45 g of (isocyanatomethyl)methoxy-dimethylsilane and 1.13 g of ε-caprolactam in 25 ml of anhydrous dioxane was heated at reflux with stirring for 4 h. The solvent was subsequently removed under reduced pressure. This gave hexahydro-N-[(methoxydimethylsilyl)methyl]-2-oxo-1H-azepine-1-carboxamide in quantitative yield with a purity of >90% (analysis by 1H NMR).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07368586B2 |
| Source dataset | uspto-grants-2008_05 |
| ORD ID | ord-b7d0c32a4fd044ec85c1ae377a20a719 |
| Source note | uspto-grants-2008_05 |