Hexane → 3-Hexanone
Reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].C([O:19]C(C1C=[C:24]2[C:29](=[O:30])N(O)C(=O)[C:25]2=[CH:32][CH:33]=1)=O)CCCCCCCCCCC>C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[CH3:1][C:2](=[O:19])[CH2:3][CH2:4][CH2:5][CH3:6].[CH3:1][CH:29]([OH:30])[CH2:24][CH2:25][CH2:32][CH3:33].[CH3:1][CH2:2][C:3](=[O:19])[CH2:4][CH2:5][CH3:6].[CH3:1][CH2:2][CH:3]([OH:19])[CH2:4][CH2:5][CH3:6]Participants
7
Reactant 2
Product 4
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 100 °C
Procedure
A mixture of 4 ml (31 mmol) of n-hexane, 0.03 mmol of 4-dodecyloxycarbonyl-N-hydroxyphthalimide, 0.0003 mmol of acetylacetonatocobalt(II) and 0.003 mmol of manganese(II) acetate was stirred at 100° C. in an atmosphere of air (10 atm=1 MPa) for 2 hours and thereby yielded 0.1 mmol of 2-hexanone, 0.09 mmol of 2-hexanol, 0.04 mmol of 3-hexanone and 0.05 mmol of 3-hexanol.
Sources & evidence
- ORD record
- ord-b19d6d1a7e5749079707ebbe64c6e7da
- Source dataset
- uspto-grants-2008_05
- Patent number
- US07368615B2
Reaction notes
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