Hydrazine → HCID 69101980, compound

HRID 2222572Notes

Reaction equation

HRID 2222572 reaction equation
C1(=O)[N:5]([CH:6]([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][N:28]=2)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][N:16]2C(=O)C3=CC=CC=C3C2=O)C(=O)C2=CC=CC=C12.NN>C(O)C>[NH2:5][CH:6]([C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][N:28]=1)[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][NH2:16]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 69101410HCID 69101410, compound

Product 1

HCID 69101980HCID 69101980, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

1,10-diphthalimido-1-pyridinyldecane (1 equiv.) and hydrazine (2 equiv.) are stirred in ethanol at reflux. The reaction mixture is cooled to room temperature and the resulting solid is filtered off. The filtrate is purified by silica gel chromatography to yield 1,10-diamino-1-pyridinyldecane.

Workup

  1. temperatureat reflux
  2. filtrationthe resulting solid is filtered off
  3. customThe filtrate is purified by silica gel chromatography

Sources & evidence

ORD record
ord-b06b8678bd64441a89d451595236f788
Source dataset
uspto-grants-2008_05
Patent number
US07371852B2

Reaction notes

Loading…