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HRID2225465

反应详情

EQUATION

反应方程式

HRID 2225465 的结构方程式

REACTANTS

反应物

2
结构：C=CC(C)(O)CCC=C(C)CCC=C(C)C
HCID8888

Nerolidol

C15H26O

结构：CC(=O)CC(=O)[O-]
HCID6971017

Acetoacetate ion(1-)

C4H5O3-

PRODUCTS

生成物

1
结构：CC(=O)CCC=C(C)CCC=C(C)CCC=C(C)C
HCID61206

5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-

C18H30O

PROCEDURE

实验过程

Nerolidol [compound (5) (manufactured by Takasago International Corporation] to be used as a starting material was subjected to Carroll reaction using acetoacetate in accordance with the method of W. Kimel et al. [J. Org. Chem., 23(2), pp. 153-157 (1958)] to give 6,10,14-trimethyl-5,9,13-pentadecatrien-2-one [compound (6)].

WORKUP

后处理

  1. customwas subjected to Carroll reaction