HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,7,11-Trimethyldodeca-1,6,10-trien-3-ol → 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,7,11-Trimethyldodeca-1,6,10-trien-3-ol | HCID 8888 | — |
| Reactant | Acetoacetate | HCID 6971017 | — |
| Product | 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl- | HCID 61206 | — |
Reaction Steps
Nerolidol [compound (5) (manufactured by Takasago International Corporation] to be used as a starting material was subjected to Carroll reaction using acetoacetate in accordance with the method of W. Kimel et al. [J. Org. Chem., 23(2), pp. 153-157 (1958)] to give 6,10,14-trimethyl-5,9,13-pentadecatrien-2-one [compound (6)].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05344850 |
| Source dataset | uspto-grants-1994_09 |
| ORD ID | ord-93f0dd2f716d436f9d9f3420594db690 |
| Source note | uspto-grants-1994_09 |