HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Octanol → 2-Octanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Octanol | HCID 20083 | — |
| Reactant | (6R,10R)-6,10,14-trimethylpentadecan-2-one | HCID 1810793 | — |
| Reactant | Sodium Hypochlorite | HCID 23665760 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 2-Octanone | HCID 8093 | 95% |
Reaction Steps
Subsequent hydrogenation (H2 /Pd-C) yields the same saturated C-18 alcohol: ##STR22## Other methods used to oxidize 2° alcohol 9 "phytone" include: (a) aqueous NaOCl (bleach) in acetic acid; such conditions give >95% yield of 2-octanone from 2-octanol. See: J. Org. Chem., 45, 2030 (1980).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05349071 |
| Source dataset | uspto-grants-1994_09 |
| ORD ID | ord-f7f2ce0ae0354762a5d8f116c7d8d963 |
| Source note | uspto-grants-1994_09 |