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HRID2226645

反应详情

EQUATION

反应方程式

HRID 2226645 的结构方程式

REACTANTS

反应物

3
结构：CCCCCCC(C)O
HCID20083

2-Octanol

C8H18O

结构：CC(=O)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
HCID1810793

未命名化合物

结构：[Na+].[O-]Cl
HCID23665760

Sodium Hypochlorite

ClNaO

PRODUCTS

生成物

1
结构：CCCCCCC(C)=O
HCID8093

2-Octanone

C8H16O

收率 95%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

Subsequent hydrogenation (H2 /Pd-C) yields the same saturated C-18 alcohol: ##STR22## Other methods used to oxidize 2° alcohol 9 "phytone" include: (a) aqueous NaOCl (bleach) in acetic acid; such conditions give >95% yield of 2-octanone from 2-octanol. See: J. Org. Chem., 45, 2030 (1980).

WORKUP

后处理

  1. customto oxidize 2°