Methyl Methacrylate → HCID 86748158, compound

HRID 2226810Notes

Reaction equation

HRID 2226810 reaction equation
[C:1]([O:5][C:6]1[CH:13]=[CH:12][C:9]([CH:10]=[CH2:11])=[CH:8][CH:7]=1)([CH3:4])([CH3:3])[CH3:2].[C:14]([O:19][CH3:20])(=[O:18])[C:15]([CH3:17])=[CH2:16].N(C(C)(CC(C)C)C#N)=NC(C)(CC(C)C)C#N>C1(C)C=CC=CC=1>[C:1]([O:5][C:6]1[CH:7]=[CH:8][C:9]([CH:10]=[CH2:11])=[CH:12][CH:13]=1)([CH3:4])([CH3:2])[CH3:3].[C:14]([O:19][CH3:20])(=[O:18])[C:15]([CH3:17])=[CH2:16]

Participants

5

Reactant 3

HCID 6658Methyl MethacrylateHCID 915372,2'-Azobis(2,4-dimethylvaleronitrile)HCID 5775311-(Tert-butoxy)-4-ethenylbenzene

Product 1

HCID 86748158HCID 86748158, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A solution of p-tert-butoxystyrene (15.8 g, 0.09 mole) and methyl methacrylate (1.0 g, 0.09 mole) in toluene containing a catalytic amount of 2,2'-azobis(2,4-dimethylvaleronitrile) was heated at 80° C. for 8 hours under nitrogen. After cooling, the reaction mixture was poured into petroleum ether and polymer was precipitated. The polymer was filtered by suction, washed with petroleum ether and dried in vacuo to give 10.9 g of poly(p-tertbutoxystyrene-methyl methacrylate) as a white powder.

Workup

  1. temperatureAfter cooling
  2. customwas precipitated
  3. filtrationThe polymer was filtered by suction
  4. washwashed with petroleum ether
  5. customdried in vacuo

Sources & evidence

ORD record
ord-e9b63df8158b49c99e5bc3926d03f394
Source dataset
uspto-grants-1994_09
Patent number
US05350660

Reaction notes

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